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Volume 15 - Issue 1

(18 Articles)

(P) ISSN:2078-8665

(E) ISSN:2411-7986

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2017 > Issue 4 > Volume 14

Synthesis and Characterization of Some Metal Complexes of [4-Methoxy-N-(pyrimidine-2-ylcarbamothioyl)benzamide]

Basima M .Sarhan | Bushra M. Fyyadh

Abstract:

A new ligand [4-Methoxy -N-(pyrimidine-2-ylcarbamothioyl) benzamide] (MPB) was synthesized by reactioniofi(4-Methoxyibenzoyliisothiocyanate)withi(2-aminopyri-midine). The Ligand was characterized by elemental micro analysis (C.H.N.S),(FT-IR) (UV- Vis) and (1Hi,13CNMR)spectra. Some transition metals complexes of this ligand were prepared and characterized by (FT-IR, UV-Vis) spectra conductivity measurements magnetic susceptibility and atomic absorption. From the obtained results the molecular formula of all complexes was suggested to be [M(MPB)2Cl2] (M+2i=Cu, Mn, Co ,Ni ,Zn ,Cd and Hg),the proposed geometrical structure for all complexes was an octahedral..

Keywords:

"2-AminoiPyrimidine, 4-Methoxy benzoyl isothiocyanate, complexes".

Published Date:03/12/2017 | Total Downloads:(11) | Doi:( http://dx.doi.org/10.21123/bsj.2017.14.4.0765 )