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Volume 15 - Issue 4

(18 Articles)

(P) ISSN:2078-8665

(E) ISSN:2411-7986

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2015 > Issue 3 > Volume 12

The Preparation of some New Mannich and Shiff bases derived from 2-Mercaptobenzimidazole

Mohammed R. Ahamed|Shetha F. Narren| Amaal S. Sadiq


The present work involved two steps: the first step include Mannich reaction was carried out on 2- mercaptobenzimidazole using formaldehyde and different secondary amine or amide to gives the compounds(2-16). The secnd step include preparation of (Ethylbenzimidazoly-2-mercaptoacetate)(17) from the reaction of 2- mercaptobenzimidazole with ethylchloroacetate than prepared hydrazide derivative[18]from reaction of compound(17) with hydrazinehydrate. Followed Preparation of shiff bases(19-24) and there reaction with mercaptoacetic acid to give a new compounds containing thiazolidinderivetives(25-30).Structure confirmation of all prepared compound were proved using FTIR and element analysis (C.H.N.S) and mesurmentedmelting point..


2Mercaptobenzimidazole, Mannich reaction, Shiff bases.

Published Date:06/09/2015 | Total Downloads:(47) | Doi:( http:// )